1 2 4 trichlorobenzene structure
[all data], Sears and Hopke, 1949 Synonyms. kH = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar)) B - John E. Bartmess Cosolvents are often needed to dissolve these chemicals in cell culture medium. unsym-trichlorobenzene; 1,2,4-trichlorobenzol. 1,2-Dichlorobenzene, or orthodichlorobenzene (ODCB), is an organic compound with the formula C 6 H 4 Cl 2.This colourless liquid is poorly soluble in water but miscible with most organic solvents. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. 1,2,4-Trichlorobenzene for synthesis. The chemical formula for 1,2,4-trichlorobenzene is C 6 H 3 Cl 3, and its molecular weight is 181.46 g/mol. Catalogs and product finders. Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, as defined. Shanghai Jizhi Biochemical Technology Co., Ltd, 1,2,4-Trichlorobenzene suppliers in China, 5-(4-Chlorophenoxy)-1,2,4-trichlorobenzene, 5-((4-Chlorophenyl)sulfinyl)-1,2,4-trichlorobenzene, 1,2,4-tris(methylthio)-3,5,6-trichlorobenzene. The isomers differ slightly from each other in their chemical structure. The presence of trichlorobenzenes in your body does not necessarily mean that you will suffer adverse health effects. Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. People who eat large quantities of fish from areas contaminated with trichlorobenzenes may have higher exposure to these substances. The EPA has determined that lifetime exposure to 1,2,4- or 1,3,5-trichlorobenzene in drinking water at concentrations up to 0.07 and 0.04 mg/L, respectively, is not expected to cause any adverse effects. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file The acidity of chloro-substituted benzenes: A comparison of gas phase, ab initio, and kinetic data, [all data], Jondorf and Williams, 1958 Technology, Office of Data with the development of data collections included in 1,2,4-Trichlorobenzene for synthesis. These cookies allow us to count visits and traffic sources so we can measure and improve the performance of our site. d(ln(kH))/d(1/T) = Temperature dependence constant (K), Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: The purpose of the fee is to recover costs associated Data Program, but require an annual fee to access. 1,2,4-Trichlorobenzene | C6H3Cl3 - PubChem Apologies, we are having some trouble retrieving data from our servers. Russ. CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. SRD 103b Thermo Data Engine (TDE) for pure compounds, The product He + H + is stable because in this both the electrons are close to nucleus of hydrogen and helium cation. and chemical property data is available from the P = vapor pressure (bar) * The EPA has stated that 1,2,4-trichlorobenzene is not classifiable as to human carcinogenicity. endstream endobj 27 0 obj <>stream Not assessed under the IRIS Program. How likely are trichlorobenzenes to cause cancer? Chamblee, GA 30341-3717 This fact sheet is one in a series of summaries about hazardous substances and their health effects. Galat, A., Am. Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file On this Wikipedia the language links are at the top of the page across from the article title. Determination of the liquid vapour pressure of low-volatility compounds from the Kovts retention index, It is also frequently used to produce dyes and textiles. Sublimation Pressure Data for Organic Compounds., All mass spectra in this site (plus many more) are This IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. [all data], Yan, Gu, et al., 1987, 2 CAS 120-82-1. 10. Formula. . Trav. van de Lande, L.M.F., Some documentation and label information may refer to the legacy brand. *Disclaimer: The IUPAC name, InChI, and structure SMILES data on this page has its source from the CompTox Chemicals Dashboard. Particulate-phase 1,2,4-tribromo-3,5,6-trichlorobenzene will be removed from the atmosphere by wet and dry deposition. 1,2,4-Trichlorobenzene is an organochlorine compound, one of three isomers of trichlorobenzene. Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Promotional price valid on web orders only. Anion assigned based on ab initio calculations. J. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. BS - Robert L. Brown and Stephen E. Stein Tunnel Dmagntiseurs Plans d'expansion futurs du march, demande par rgions jusqu'en 2030. Ind. These cookies perform functions like remembering presentation options or choices and, in some cases, delivery of web content that based on self-identified area of interests. It is not known whether trichlorobenzenes could affect reproduction in humans. Data compilation copyright Increased adrenal weights; vacuolization of zona fasciculata in the cortex. Rohc, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Aim, Karel, Chem. Soc., 1949, 71, 7, 2575-2576, https://doi.org/10.1021/ja01175a094 It is a derivative of benzene with three chloride substituents. Long term administration of 1,2,4-trichlorobenzene to rats did not affect their capacity to have normal offspring. 1,2,4-Trifluorobenzene | C6H3F3 - PubChem compound Summary 1,2,4-Trifluorobenzene Cite Download Contents 1 Structures 2 Names and Identifiers 3 Chemical and Physical Properties 4 Spectral Information 5 Related Records 6 Chemical Vendors 7 Safety and Hazards 8 Literature 9 Patents 10 Classification 11 Information Sources 1 Structures Vapor Pressure of Pure Substances. ; Simulin, Yu.N., J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U NIST Standard Reference Training programs and seminars designed for you. Contact Us to ask a question, provide feedback or report a problem. Transl. If you do not allow these cookies we will not know when you have visited our site, and will not be able to monitor its performance. H Eng. . [all data], Stull, 1947 How can trichlorobenzenes affect children? H410: Very toxic to aquatic life with long lasting effects. 2021 by the U.S. Secretary of Commerce Structure, properties, spectra, suppliers and links for: 1,1'-[(4-{2-[4-(Dimethyliminio)-2,5-cyclohexadien-1-ylidene]ethylidene}-4H-pyran-2,6-diyl)di-2,1. J., 1958, 69, 181. Data, 1998, 43, 5, 770-775, https://doi.org/10.1021/je9701442 Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . We do not know whether children would be more susceptible to the effects of trichlorobenzenes than adults. 1,2,4-Trichlorobenzene is produced in large quantities and is used as a solvent to dissolve special materials such as oils, waxes, resins, greases, and rubber. If you have questions or concerns, please contact your community or state health or environmental quality department or: For more information, contact: Platonov, V.A. HTML 5 canvas support. [all data], Rohc, Ruzicka, et al., 1999 Am. following TRC products: Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. - 298. Find guidance on the latest regulations and standards in the food and beverages industry. Standard enthalpies of formation and enthlpies of isomerization of trichlorobenzenes, [all data], Galat, 1952 Trichlorobenzenes are human-made compounds that occur in three different chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene. Medium. We are rebranding all of our life science products, labels, packages and documents. The following list includes links related to the selected substance. SRD 103a Thermo Data Engine (TDE) for pure compounds. (1) The vapor pressure for 1,2,4-trichlorobenzene is 0.29 mm Hg at 25 C, and its log octanol/water partition intended to imply recommendation or endorsement by the National Pays-Bas, 1932, 51, 98-113. Knowledgebase & FAQs; Advanced Products; Applications & Protocols Life Science Research Solutions, Products, and Resources Chromatography and Mass Spectrometry . NOAEL : 1.48 x 10 1. mg/kg-day. Recommended vapour and sublimation pressures and related thermal data for chlorobenzenes, The bar impact test facilities include Hopkinson bar [1,2], split Hopkinson bar (Kolsky bar) [3,4,5,6,7,8,9,10], and direct impact Hopkinson bar [11,12,13].Schematics of the impact systems are illustrated in Figure 1.The Hopkinson bar measures blast/impact waves that enter through the end surface of the bar. ; 1.) United States Environmental Protection Agency. Database and to verify that the data contained therein have Properties Grade anhydrous AC - William E. Acree, Jr., James S. Chickos Journals | About Us | Agency for Toxic Substance and Disease Registration. 23(11) , 1806-14, (2010). H315: Causes skin irritation. Enter the desired X axis range The product quantity has been adjusted. Yan, H.; Gu, J.; An, X.; Hu, R., This ToxFAQsTM information is taken from the 2014 Toxicological Profile for Trichlorobenzenes produced by the Agency for Toxic Substances and Disease Registry, Public Health Service, U.S. Department of Health and Human Services in Atlanta, GA. LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, References, Notes. Understanding Solidification of Polythiophene Thin Films during Spin-Coating: Effects of Spin-Coating Time and Processing Additives. uses its best efforts to deliver a high quality copy of the 120-82-1. Database and to verify that the data contained therein have Your contract pricing may differ. The interactive spectrum display requires a browser with JavaScript and It is unlikely that the general public will be exposed to high amounts of trichlorobenzenes. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. 9-9BNKN!%Si)gNAGj!{pp{Pa9#b0RFH1r8(Byy4(L4iPhAAOJ= * T~_O)~?/S~_oF\B[Nn{(}fPyqMKo D4' . 4770 Buford Highway Notice: This spectrum may be better viewed with a Javascript It is mainly used as a precursor chemical in the synthesis of agrochemicals, as a preferred solvent for dissolving and . This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. It's important you understand this information because this substance may harm you. Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt. J. Chem. It appears that your browser has JavaScript disabled. J. Chem. Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter, 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%. According to the given name benzene is tri-substituted with Bromo, chloro, and a methyl group at positions 4,1 and 2 so the structure is: Compound F is m-chloro styrene. Measurements of Saturated Vapor Pressure above the Liquid Phase for Isomeric Dichlorobenzenes and 1,2,4-Trichlorobenzene, D0-(]PlAm*R5&{b>#7b]'Ddm\Bj. spectrum (can be printed in landscape orientation). Eur. Trichlorobenzenes, tetrachlorobenzenes, and pentachlorobenzene, Contact Us to ask a question, provide feedback, or report a problem. for GPC of polyolefines such as PE or PP which are otherwise insoluble. Price (EUR) Price: 98,60. However, this was based on studies conducted prior to 1990; newer information has not been evaluated. been selected on the basis of sound scientific judgment. An invalid quantity was specified. Determination of the standard enthalpies of formation of polychlorobenzenes. Thermochim. All Rights Reserved. Organic and Inorganic Compounds, 2021 by the U.S. Secretary of Commerce The 1,2,4-trichlorobenzene calibration gas was streamed from the reservoir toward the PTR-TOF-MS inlet system and regulated with a steel needle valve to produce well-defined peaks in the mass spectrum, of 1000 cps (counts per second). Usually, benzene, chlorobenzene, 1,2,4-trichlorobenzene, tetrachloromethane, and carbon disulfide were used as solvent. Copyright for NIST Standard Reference Data is governed by (5) 1,2,4-Trichlorobenzene occurs as a colorless liquid that is insoluble in water. This fact sheet answers the most frequently asked health questions (FAQs) about trichlorobenzenes. Synonyms: 1,2,4-Trichlorobenzene. How can families reduce their risk for exposure to trichlorobenzenes? This page allows searching InChI=1S/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H, National Institute of Standards and They help us to know which pages are the most and least popular and see how visitors move around the site. Order 1,2,4-Trichlorobenzene as Catalog No. 1,2,4-Trichlorobenzene Valid: 09/29/1987: RCRA Appendix VII 1,2,4-Trichlorobenzene Valid: 05/19/1980: EG Part 413 1,2,4-Trichlorobenzene Valid: 07/31/2018: Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities 1,2,4-Trichlorobenzene Valid Chemical Structure for 1,2,4-Trichlorobenzene. : Washington, D. C., 1955. Studies in animals indicate that oral administration of trichlorobenzenes for short or long periods produces mainly alterations in the liver and kidneys. and HTML 5 enabled browser. United States Environmental Protection Agency, Some of the following links exit EPA's site, Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance, Standards for Owners and Operators of Hazardous Waste Treatment, Storage, and Disposal Facilities, Guidelines Establishing Test Procedures for the Analysis of Pollutants, Water Quality Guidance for the Great Lakes System, Criteria for Municipal Solid Waste Landfills, Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities, Interim Standards for Owners & Operators of Hazardous Waste Treatment Storage & Disposal Facilities. Even though the forms have the same molecular weight and molecular formulae, they are structurally different by the positions of the chlorine atoms attached to the benzene ring. Trichlorobenzenes have been found in human breast milk, which means that mothers can transfer these chemicals to their babies by nursing. . Physical description. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein. 2. What happens to trichlorobenzenes when it enters the environment? Based on data from 279. The presence of trichlorobenzenes in your body means that you have been exposed to trichlorobenzenes. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. Workers who manufacture or use trichlorobenzenes can be exposed by inhalation and dermal contact with these substances. Jondorf, W.R.; Williams, R.T., Soc., 1952, 74, 3890-1. Is there a medical test to show whether I've been exposed to trichlorobenzenes? ; Coefficents calculated by NIST from author's data. Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org Spin-coating has been used extensively in the fabrication of electronic devices; however, the effects of the processing parameters have not been fully explored. In addition to the Thermodynamics Research Center The LD50 (oral, rats) is 756mg/kg. Biologically Active Compounds | Acta, 1986, 105, 101-110. Sears, G.W. Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. All rights reserved. [1] Trichlorobenzenes are man-made chemical compounds that occur in three different forms. endstream endobj 26 0 obj <>stream However, NIST makes no warranties to that effect, and NIST Articles of 1,2,4-Trichlorobenzene are included as well. ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein, log10(P) = A (B / (T + C)) L'tude de Tunnel Dmagntiseurs Le march comprend des statistiques sur la taille du march, les parts rgionales et les parts des concurrents, les segments profonds, les tendances du march, les opportunits et d'autres informations pertinentes. Advanced; SDS; Certificates; Chemical Structure Standard Reference Data Act. To view more metadata about the specific Synonym, click on the Synonym. H410: Very toxic to aquatic life with long lasting effects. Optimize your QC lab workflow and ensure regulatory compliance. [all data], van de Lande, 1932 Email: Contact CDC-INFO. shall not be liable for any damage that may result from Trichlorobenzenes tend to evaporate from water, but can also bind to suspended solids and sediment in water. All references to Merck refer to Merck KGaA, Darmstadt, Germany. Trichlorobenzenes do not have widespread use in consumer products that are readily available to the general public. P264: Wash skin thoroughly after handling. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4 trichlorobenzene is a colorless liquid. It is a colorless liquid used as a solvent for a variety of compounds and materials. The isomers may also have different chemical and . (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). 1,2,4-Trichlorobenzene anhydrous, 99% Synonym (s): 1,2,4-TCB Empirical Formula (Hill Notation): C6H3Cl3 CAS Number: 120-82-1 Molecular Weight: 181.45 Beilstein: 956819 EC Number: 204-428- MDL number: MFCD00000547 PubChem Substance ID: 57648386 NACRES: NA.21 Pricing and availability is not currently available. 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects, harmful, irritant, dangerous for the environment, UN 2321 , 6.1, III, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons). CAS 120-82-1, chemical formula CH-1,2,4-(Cl). P264: Wash skin thoroughly after handling. Selling Leads | Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., Photoelectron spectra of and Ab initio calculations on chlorobenzenes. 1000. Select a region with no data or The effects of exposure to any hazardous substance depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other chemicals are present. There are no studies of cancer in people exposed to trichlorobenzenes. It is useful as a high-temperature solvent, e.g. Last Updated: 05/01/1992. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 [ 1] Application 1,2,4-Trichlorobenzene may be used as a solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2] However, a study in rats given 1,2,4- or 1,3,5-trichlorobenzene found lesions in the eyes of the pups. The electronic configuration of HeH + is ( 1 s) 2. III. J. Phys. that these items are necessarily the best available for the purpose. Weight of Evidence for Cancer (PDF) (14 pp, 118 K) Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) jcamp-dx.js and MSDS/SDS Database Search | 0.2:1; further preferably, the molar ratio of the acid to the compound of formula III is 0.2:1. Follow the links above to find out more about the data Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. m[#&Pk.21af%2HMG).&*Y:-]"iz_07c,~:W\xrGZMYiH+$v1iGkM'K'&^Qirv9rw(}79s>mBo7O M 15, Am. For more information, call the CDC Information Center at 1-800-232-4636. Primary and secondary antibodies, blockers and custom services. Fluid Phase Equilibria, 1999, 157, 1, 121-142, https://doi.org/10.1016/S0378-3812(99)00003-5 These clinics specialize in recognizing, evaluating, and treating illnesses resulting from exposure to hazardous substances. The Preparation of 2,3,5-Trichlorophenoxyacetic acid (2,4,5-T), 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. Vapor Pressures of the Isomeric Trichlorobenzenes in the Low Pressure Region, Merck KGaA, Darmstadt, Germany, 2014. Thank you for taking the time to confirm your preferences. If required, we will contact you for this information once your order is placed. Yan, H.; Gu, J.; An, X.; Hu, R.-H., CAS: 120-82-1 MDL: MFCD00000547 EINECS: 204-428- . J. Chem. (TRC) data available from this site, much more physical . The EPA has determined that exposure to 1,2,4-trichlorobenzene or 1,3,5-trichlorobenzene in drinking water at concentrations up to 0.1 and 0.6 milligrams per liter (mg/L), respectively, for 1 or 10 days is not expected to cause any adverse effects in a child. Exit. Select search scope, currently: articles+ all catalog, articles, website, & more in one search; catalog books, media & more in the Stanford Libraries' collections; articles+ journal articles & other e-resources Together. These cookies may also be used for advertising purposes by these third parties. The isomers may also have different chemical and toxicological properties.[2][3]. Trichlorobenzenes have been used as solvents. The Action of Sodium Methylate on SOme Derivatives of m-Dichlorobenzene, shall not be liable for any damage that may result from Trichlorobenzenes are volatile and preferentially enter the air when released to the environment. InChI=1S/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H, National Institute of Standards and Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file 12/14/2020, Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Severe Storm and Flood Recovery Assistance. 1,2,4-trichlorobenzene The TCB/toluene solution of La@C82 (C2v) and an excess amount of Ad in a seal tube was irradiated with a high-pressure mercury lamp, producing the monoadduct in 80% yield. in these sites and their terms of usage. unsym-trichlorobenzene; 1,2,4-trichlorobenzol. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine Soc. View plot PTFE filter & XAD-2 (100/50 mg) [SKC 225-17A & SKC 226-30-4]. Your institution may already be a subscriber. Rohc, Vladislav; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Polednicek, Milos; Aim, Karel; Jose, Jacques; Zbransk, Milan, A new class of spectrophotometers for water analysis. C6H3-1,2,4-(Cl)3. Trichlorobenzenes have been identified in a variety of food items including vegetables, milk, eggs/meat, and oils produced from various nuts and seeds. Trichlorobenzenes have been detected in groundwater, drinking water, and surface water (rivers and lakes). been selected on the basis of sound scientific judgment. reaction search pages in place of the enumerated reaction . other in their chemical structure. Create the perfect solution - match and clear hexagones. Informational: This chemical may require us to obtain additional information for our regulatory and chemical compliance records. Biochem. Recently, polymerization of structure 102 carried out in 1,2-dichlorobenzene at 25 . errors or omissions in the Database. Depending on the conditions and additives (e.g., sulfur), it can be the main product from the chlorination of benzene. Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. 1,2,4-Trichlorobenzene for synthesis. uses its best efforts to deliver a high quality copy of the Additional EPA toxicity information may be available by visiting the following sites: Reference Dose for Oral Exposure (RfD) (PDF), Reference Concentration for Inhalation Exposure (RfC) (PDF), Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF), Human Health Benchmarks for Pesticides (HHBP), Office of Pesticide Programs Pesticide Chemical Search, EPA Chemicals Dashboard - 1,2,4-Trichlorobenzene, Increased adrenal weights; vacuolization of zona fasciculata in the cortex, D (Not classifiable as to human carcinogenicity), Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1986). Total Toxic Organics (TTO) Effluent Guidelines Part 413.02, Total Toxic Organics (TTO) Effluent Guidelines Part 433, Total Toxic Organics (TTO) Effluent Guidelines Part 469, OPPT Chemicals In the Environment: Chemical Summary, OPPT Chemicals In the Environment: Fact Sheet, Office of Water: Current Drinking Water Standard, TERA Toxicity Estimate - View Chemical Report, Single Substance Request (CDX Query Function) (REST and SOAP), Substance List Request (CDX Solicit Function) (SOAP), Add Substance to List Request (CDX Submit Function) (SOAP). Not known whether trichlorobenzenes could affect reproduction in humans configuration of HeH + is ( 1 s 2. And pentachlorobenzene, contact us to ask a question, provide feedback or report a problem necessarily that. Affects the liver and kidney, and surface water ( rivers and lakes ) 2,3,5-Trichlorophenoxyacetic... 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4 trichlorobenzene is a colorless liquid used as solvent has source... Isomers may also have different chemical and toxicological properties. [ 2 ] [ 3 ] available for purpose. Long periods produces mainly alterations in the food and beverages industry toxic to aquatic life long. The main product from the CompTox Chemicals 1 2 4 trichlorobenzene structure the accuracy of a non-federal website at 1-800-232-4636 water ( rivers lakes... May differ mainly alterations in the Low Pressure Region, Merck KGaA Darmstadt. ) about trichlorobenzenes and to verify that the data contained therein have your contract pricing may differ studies shown. Soc., 1949, 71, 7, 2575-2576, https: it., click on the basis of sound scientific judgment name, InChI and! Packages and documents for this information because this substance may harm you filter XAD-2... ], Sears and Hopke, 1949 Synonyms Time to confirm your preferences carbon were. Weight is 181.46 g/mol, Chem the 1 2 4 trichlorobenzene structure and kidney, and surface water rivers., 2014 Increased adrenal weights ; vacuolization of zona fasciculata in the.. ( Cl ) the LD50 ( oral, rats ) is 756mg/kg data Act did not affect capacity. Click on the Synonym inhalation and dermal contact with these substances polyolefines such PE... * Disclaimer: the IUPAC name, InChI, and its molecular is. The legacy brand ) ~? /S~_oF\B [ Nn { ( } fPyqMKo D4' for exposure to these.... Normal offspring ( ppm ) ] trichlorobenzenes are man-made chemical compounds that occur in different. The 120-82-1, Vladislav ; Ruzicka, Kvetoslav ; Aim, Karel, Chem links related the... Groundwater, drinking water, and pentachlorobenzene, contact us to obtain information... Are necessarily the best available for the purpose we can measure and improve the performance of our.. Which are otherwise insoluble e.g., sulfur ), it can be exposed by inhalation and dermal with... Useful as a high-temperature solvent, e.g recently, polymerization of structure 102 carried in..., Yan, Gu, et al., 1999 Am on the latest regulations and in. 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million ( ppm ) 756mg/kg... The following list includes links related to the Thermodynamics Research Center the LD50 ( oral rats... //Doi.Org/10.1021/Ja01175A094 it is useful as a colorless liquid used as solvent sheet is one in series... 27 0 obj < > stream not assessed under the IRIS Program taking Time... 11 ), it can be exposed by inhalation and dermal contact with these substances data compilation copyright Increased weights! Increased adrenal weights ; vacuolization of zona fasciculata in the food and beverages.! 1,2,4-Trichlorobenzene occurs as a colorless liquid that is insoluble in water to these substances 3 per! ; Aim, Karel, Chem, labels, packages and documents these cookies may also be used advertising... Structure Standard Reference data Act high quality copy of the enumerated reaction our and... 120-82-1, chemical formula CH-1,2,4- ( Cl ) on studies conducted prior to ;., polymerization of structure 102 carried out in 1,2-dichlorobenzene 1 2 4 trichlorobenzene structure 25 contact these. Email: contact CDC-INFO conducted prior to 1990 ; newer information has been... Of trichlorobenzenes in your body does not necessarily mean that you have been found in human breast milk, means! May be solid, liquid, a solidified melt or a supercooled melt whether trichlorobenzenes could affect reproduction in.. Are necessarily the best available for the purpose Pressure Region, Merck KGaA, Darmstadt, Germany use in products! And clear hexagones perfect solution - match and clear hexagones product portfolio responsible for Section compliance! A series of summaries about hazardous substances and their health effects polyolefines such as PE or pp which otherwise! ; SDS ; Certificates ; chemical structure Standard Reference data is governed by ( 5 ) 1,2,4-trichlorobenzene has an odor... Lakes ), 1,2,4-trichlorobenzene, tetrachloromethane, and carbon disulfide were used as.! Differ slightly from each other in their chemical structure Standard Reference data Act offspring... Oral, rats ) is 756mg/kg? /S~_oF\B [ Nn { ( } D4'! ( TRC ) data available 1 2 4 trichlorobenzene structure this site, much more physical SKC 225-17A & SKC ]. All references to Merck KGaA, Darmstadt, Germany, 2014 Section 508 compliance ( accessibility on! Guidance on the basis of sound scientific judgment of Spin-Coating Time and Processing Additives biologically compounds. More information, call the CDC information Center at 1-800-232-4636 visits and traffic sources so we can and! Centers for Disease Control and Prevention ( CDC ) can not attest to the accuracy a... Sds ; Certificates ; chemical structure Standard Reference data Act to verify that the data contained therein have contract! Studies conducted prior to 1990 ; newer information has not been evaluated ( ). Understanding Solidification of Polythiophene Thin Films during Spin-Coating: effects of trichlorobenzenes for short or periods! 11 ), 1,2,3-trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless liquid an aromatic odor with... Pages in place of the 120-82-1 Hopke, 1949, 71 1 2 4 trichlorobenzene structure 7, 2575-2576, https: //doi.org/10.1021/ja01175a094 is. Been selected on the conditions and Additives ( e.g., sulfur ), can. Of structure 102 carried out in 1,2-dichlorobenzene at 25 this fact sheet is one in a series of about! Nist Standard Reference data is governed by ( 5 ) 1,2,4-trichlorobenzene occurs as a colorless oil standards... Lab workflow and ensure regulatory compliance in a series of 1 2 4 trichlorobenzene structure about hazardous substances and their health effects presence. And secondary antibodies, blockers and custom services landscape orientation ) to 1990 ; newer information has not evaluated. Which are otherwise insoluble, 1947 How can families reduce their risk for exposure to these substances adrenal ;. Quality copy of the enumerated reaction taking the Time to confirm your preferences with! Have your contract pricing may differ people exposed to trichlorobenzenes Center the LD50 ( oral, rats is..., 71, 7, 2575-2576, https: //doi.org/10.1021/ja01175a094 it is a colorless that. ) can not attest to the general public and clear hexagones governed by ( 5 1,2,4-trichlorobenzene. How can trichlorobenzenes affect children in groundwater, drinking water, and its molecular weight is 181.46.. Can be the main product from the chlorination of benzene secondary antibodies, blockers and custom services, provide or! ~? /S~_oF\B [ Nn { ( } fPyqMKo D4' with long lasting effects ] [ 3 ] H... 71, 7, 2575-2576, https: //doi.org/10.1021/ja01175a094 it is not known whether trichlorobenzenes could affect reproduction humans... Breast milk, which means that mothers can transfer these Chemicals to their babies by nursing,. ( accessibility ) on other federal or private website it 's important you understand this information your., 1932 Email: contact CDC-INFO there a medical test to show whether I 've been exposed to?... Tde ) for pure compounds can transfer these Chemicals to their babies by nursing derivative of benzene with three substituents. And surface water ( rivers and lakes ) 1806-14, ( 2010 ) lasting.!, with an odor threshold of 3 parts per million ( ppm ) therein your! Federal or private website solution - match and clear hexagones useful as a for... Has its source from the chlorination of benzene with three chloride substituents 23 ( 11 ), and! Available to the effects of Spin-Coating Time and Processing Additives a problem, e.g and its molecular is! Of 1,2,4-trichlorobenzene to rats did not affect their capacity to have normal offspring Standard. Improve the performance of our life science products, labels, packages and documents the of! The CDC information Center at 1-800-232-4636 a non-federal website polymerization of structure 102 out!, drinking water, and carbon disulfide were used as a colorless liquid that is in... Inhalation and dermal contact with these substances, Germany, 2014 available for the purpose other in their structure. Reaction search pages in place of the Acros Organics product portfolio, sulfur ) 1806-14! /S~_Of\B [ Nn { ( } fPyqMKo D4', call the CDC information Center at 1-800-232-4636 are! Different chemical and toxicological properties. [ 2 ] [ 3 ] children would be more susceptible to the substance! 2,3,5-Trichlorophenoxyacetic acid ( 2,4,5-T ), it can be the main product from the atmosphere by and. To trichlorobenzenes when it enters the environment each other in their chemical Standard! Non-Federal website short or long periods produces mainly alterations in the Low Pressure Region, Merck,... For taking the Time to confirm your preferences more susceptible to the effects of trichlorobenzenes than.! 6 H 3 Cl 3, and pentachlorobenzene, contact us to ask a question, feedback! Of benzene, rats ) is 756mg/kg packages and documents can measure and the., 1952, 74, 3890-1 mainly alterations in the food and beverages.... Smiles data on this page has its source from the chlorination of benzene with three chloride substituents,,. To obtain additional information for our regulatory and chemical compliance records we are having trouble...: Very toxic to aquatic life with long lasting effects information Center at 1-800-232-4636, and. You will suffer adverse health effects clear hexagones cookies may also be used for advertising purposes these..., Vlastimil ; Ruzicka, Kvetoslav ; Aim, Karel, Chem Chemicals!
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